Patent No. EP3523334 (titled "Process For Manufacturing Polyethylene") was filed by Akzo Nobel Chemicals International BV on Sep 28, 2017. The application was issued on Nov 15, 2023.
A process for manufacturing polyethylene homo- or copolymers via high-pressure polymerization of ethylene, optionally with co-monomers, is conducted in a tubular reactor at temperatures between 160-350°C. Tert-amyl peroxyisobutyrate serves as the polymerization initiator and is introduced along the tube length at 2 to 6 inlet points, creating 2 to 6 distinct reaction zones for initiation. The initiator is preferably added in amounts of 100-1000 ppm (more preferably 100-500 ppm) based on polyethylene weight. The process may utilize co-initiators of higher reactivity (e.g., tert-butyl peroxypivalate, di(2-ethylhexyl)peroxydicarbonate, tert-butyl peroxyneodecanoate) or lower reactivity (e.g., di-tert-butyl peroxide, tert-butyl peroxy-3,3,5-trimethylhexanoate). The tubular reactor typically includes a cooling jacket to manage reaction heat.

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