Patent No. EP4288383 (titled "Process And Plant For Methanol Production") was filed by Casale on Jan 26, 2022. The application was issued on Sep 11, 2024.
A process for methanol synthesis that enables efficient operation with sub-stoichiometric syngas and high methane content. The process involves dual hydrogen recovery: a first stream is obtained through water-gas shift and hydrogen purification of a partially cooled make-up gas, while a second stream is recovered from the methanol synthesis loop purge gas. This dual recovery enables flexible control of hydrogen content in the main make-up gas stream, allowing for efficient methanol synthesis even with sub-stoichiometric syngas and high methane content.

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