Patent No. EP4495149 (titled "Propylene Polymers For Three-Dimensional Printing") was filed by Lummus Novolen Technology on Jul 18, 2024. The application was issued on Dec 3, 2025.
This propylene copolymer composition for 3D printing (FFF and APF) comprises 70–95 wt% propylene and 3.0–25 wt% of at least two $\alpha$-olefin comonomers selected from ethylene, 1-butylene, 1-pentene, 1-hexene, 1-heptene, and 1-octene, as determined by FTIR. The comonomer with the lower molar mass is present at 0.3–10 wt%. Technical specifications include a melt flow rate (MFR) of 5.4–250 g/10 min (ISO 1133, 230°C, 2.16 kg), a polydispersity index (PI) of 1.0–3.7 (determined via rheological oscillatory frequency sweep at 210°C where $PI = 10^5\text{ Pa}/G_c$), and an analytical temperature rising elution fractionation full width at half maximum (ATREF FWHM) of 1.0–15.4°C determined by CRYSTAF-TREF in 1,2-dichlorobenzene using a specific cooling/heating

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