Biodegradable, Industrially Compostable, And Recyclable Injection Molded Microcellular Flexible Foams

Patent No. US11718055 (titled "Biodegradable, Industrially Compostable, And Recyclable Injection Molded Microcellular Flexible Foams") was filed by Ing Capital Llc on Oct 7, 2022.

What is this patent about?

’055 is related to the field of manufacturing flexible foams, specifically addressing the environmental concerns associated with traditional foam production. Conventional flexible foams often rely on non-renewable resources, chemical blowing agents, and crosslinking, leading to materials that are difficult to recycle or biodegrade and contribute to landfill waste.

The underlying idea behind ’055 is to create a recyclable flexible foam using a modified injection molding process. This involves using a thermoplastic polymer derived from recyclable materials and a supercritical fluid (SCF) , such as nitrogen or carbon dioxide, as a physical foaming agent instead of chemical blowing agents. The key is to form a single-phase solution of the polymer and SCF, inject it into a mold, and control the foaming process with gas counter pressure.

The claims of ’055 focus on a method for manufacturing a flexible foam. This method involves forming a molten polymer from a recyclable thermoplastic masterbatch, mixing it with a supercritical fluid to create a single-phase solution, introducing this solution into a mold cavity, foaming the solution by allowing the supercritical fluid to come out of solution, and pressurizing the mold cavity with a counterpressure gas . The dosing and hold time of this counterpressure gas are controlled by a computer based on pressure sensor data.

In practice, the thermoplastic polymer, potentially derived from recycled sources like fishing nets or carpet fibers, is melted and mixed with the SCF in a modified injection molding machine. The SCF, acting as a blowing agent, creates the foam structure. The gas counter pressure is crucial for controlling the expansion of the foam, ensuring a smooth surface finish and preventing defects. Dynamic mold temperature control further optimizes the cell structure of the foam.

This approach differs significantly from traditional foam manufacturing, which often uses chemical blowing agents that result in crosslinked polymers, making recycling difficult. By using a physical blowing agent (SCF) and carefully selected thermoplastic polymers, ’055 enables the creation of a flexible foam that can be depolymerized and recycled back into its constituent monomers, closing the loop and reducing reliance on virgin materials. The resulting foam can be used in various applications, including footwear, furniture, and automotive components.

How does this patent fit in bigger picture?

Technical landscape at the time

In the late 2010s when ’055 was filed, flexible foams were typically manufactured using non-renewable materials and chemical blowing agents. At a time when crosslinking was commonly used to achieve desired foam properties, the resulting products were often not biodegradable, compostable, or recyclable. The industry standard relied on petrochemical-derived polymers, and hardware or software constraints made it non-trivial to produce foams with both high performance and environmental sustainability.

Novelty and Inventive Step

The examiner approved the application because the prior art does not teach a method for manufacturing a flexible foam that includes: forming a molten polymer from a thermoplastic masterbatch comprising recyclable thermoplastic polymers; mixing a supercritical fluid with the molten polymer to create a single-phase solution; introducing the single-phase solution into a mold cavity with at least one pressure sensor; foaming the single-phase solution by allowing the supercritical fluid to come out of solution; and pressurizing the mold cavity with a counterpressure gas controlled by a computer-controller receiving data from the pressure sensor.

Claims

This patent contains 20 claims, with claim 1 being the only independent claim. Independent claim 1 is directed to a method for manufacturing a flexible foam using a thermoplastic masterbatch and supercritical fluid. The dependent claims elaborate on specific materials, conditions, and features of the method described in the independent claim.

Key Claim Terms New

Definitions of key terms used in the patent claims.

Term (Source)Support for SpecificationInterpretation
Counterpressure gas
(Claim 1)
“Gas counter pressure (GCP) is also utilized in the process to ensure optimal foam structure with little to no skin on the resulting flexible foam. GCP can best be described as a process that includes a pressurized mold cavity that is injected with nitrogen gas to counteract the expansion of the gas within the melt. As the counter pressure is released, the gas bubbles that would conventionally breakthrough the surface are trapped inside, creating a smooth skin. The GCP controls the foaming through surface quality, foam structure, and skin thickness.”A gas used to pressurize the mold cavity during foaming, controlling the expansion of the single-phase solution and the resulting foam structure.
Single-phase solution
(Claim 1)
“The creation of the single-phase solution, in which the SCF is fully dissolved and uniformly dispersed in the molten polymer, takes place inside the injection barrel under carefully controlled process conditions: the SCF must be accurately mass flow metered into the polymer for a fixed amount of time. And during that dosing period, the right conditions of temperature, pressure and shear must be established within the barrel. Back-pressure, screw-speed and barrel-temperature control, as well as gas counter pressure and SCF delivery system all play a role in establishing the process conditions that create the single-phase solution.”A mixture of molten polymer and supercritical fluid, where the supercritical fluid is fully dissolved and uniformly dispersed within the polymer.
Supercritical fluid
(Claim 1)
“Specifically, a supercritical fluid is a substance (liquid or gas) that is in a state above its critical temperature (Tc) and critical pressure (Pc). At this critical point gases and liquids coexist, and a supercritical fluid shows unique properties that are different from those of either liquids or gases, e.g., under standard conditions. It is advantageous to use inert supercritical fluid, such as nitrogen, CO2, He, Ne, Ar, Xe, and other such inert gasses, such as in a supercritical fluid state, which gasses that may be employed in accordance with the methods disclosed herein as a blowing agent in the foaming process.”A substance (liquid or gas) that is in a state above its critical temperature and critical pressure, used to create cell nuclei in the molten polymer.
Thermoplastic masterbatch
(Claim 1)
“Additionally, blends of two or more thermoplastic polymers provide a combination of properties and price not found in a single polymer. There are a number of ways to blend polymers together successfully. One method may use twin-screw extrusion to melt two or more polymer resins together and to then extrude the molten polymer resin blend into a strand that is cooled and fed into a pelletizer for producing an array of pelletized pieces called a masterbatch.”A blend of one or more recyclable thermoplastic polymers used as a starting material for forming the molten polymer.

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US11718055

ING CAPITAL LLC
Application Number
US17938790
Filing Date
Oct 7, 2022
Status
Granted
Expiry Date
May 21, 2039
External Links
Slate, USPTO, Google Patents