Biodegradable, Industrially Compostable, And Recyclable Injection Molded Microcellular Flexible Foams

Patent No. US12194704 (titled "Biodegradable, Industrially Compostable, And Recyclable Injection Molded Microcellular Flexible Foams") was filed by O2 Partners Llc on Aug 7, 2023.

What is this patent about?

’704 is related to the field of manufacturing flexible foams, specifically addressing the environmental concerns associated with traditional foam production. Conventional flexible foams often rely on non-renewable materials, chemical blowing agents, and crosslinking, leading to products that are difficult to recycle and contribute to landfill waste. The patent aims to provide a process for creating recyclable foams using more sustainable methods and materials.

The underlying idea behind ’704 is to use a supercritical fluid (SCF) , such as nitrogen or carbon dioxide, as a physical blowing agent in conjunction with recyclable thermoplastic polymers. This eliminates the need for chemical blowing agents and crosslinking, which hinder recyclability. The SCF is mixed with the molten polymer to create a single-phase solution, which is then injected into a mold. The pressure drop in the mold causes the SCF to come out of solution, creating the foam structure.

The claims of ’704 focus on a method for manufacturing a flexible foam. The method involves forming a molten polymer from a thermoplastic masterbatch containing recyclable thermoplastic polymers, mixing a supercritical fluid with the molten polymer to create a single-phase solution, introducing the solution into a mold cavity pressurized with a counterpressure gas, and foaming the solution by allowing the supercritical fluid to come out of solution. A key aspect is that the thermoplastic polymers do not cross-link during manufacturing.

In practice, the process involves carefully controlling several parameters. The thermoplastic polymer is melted and mixed with the SCF in a specialized injection molding machine. The gas counter pressure is used to control the expansion of the foam and prevent surface defects. Dynamic mold temperature control is employed to ensure consistent cell structure. The resulting foam can then be used in various applications, such as shoe midsoles, furniture cushioning, and automotive components.

The differentiation from prior approaches lies in the combination of using recyclable thermoplastic polymers, a supercritical fluid as a blowing agent, and the absence of crosslinking. This allows the resulting foam to be recycled at the end of its life, closing the loop and reducing environmental impact. The use of gas counter pressure and dynamic mold temperature control further enhances the quality and consistency of the foam structure, making it a viable alternative to traditional, less sustainable flexible foams.

How does this patent fit in bigger picture?

Technical landscape at the time

In the late 2010s when ’704 was filed, at a time when flexible foams were typically manufactured using chemical blowing agents and crosslinking processes, resulting in materials that were difficult to recycle or compost. Systems commonly relied on petroleum-derived polymers rather than bio-derived alternatives for flexible foam production. Hardware or software constraints made the precise control of foam cell structure and density during injection molding non-trivial.

Novelty and Inventive Step

Claims 10-29 were pending in the application. Claims 10-29 were rejected for nonstatutory double patenting over two US patents. Claims 10, 11, and 16-19 were rejected under 35 U.S.C. 102(a)(2) as being anticipated by SUZUKI. The prosecution record does NOT describe the technical reasoning or specific claim changes that led to allowance.

Claims

This patent contains 20 claims, with independent claims numbered 1, 17, and 20. The independent claims are directed to methods for manufacturing flexible foam using a thermoplastic masterbatch and supercritical fluid. The dependent claims generally elaborate on the composition of the thermoplastic polymers, the supercritical fluid, the pressure ranges, and the control systems used in the method.

Key Claim Terms New

Definitions of key terms used in the patent claims.

Term (Source)Support for SpecificationInterpretation
Counterpressure gas
(Claim 1, Claim 17, Claim 20)
“Gas counter pressure (GCP) is also utilized in the process to ensure optimal foam structure with little to no skin on the resulting flexible foam. GCP can best be described as a process that includes a pressurized mold cavity that is injected with nitrogen gas to counteract the expansion of the gas within the melt. As the counter pressure is released, the gas bubbles that would conventionally breakthrough the surface are trapped inside, creating a smooth skin. The GCP controls the foaming through surface quality, foam structure, and skin thickness.”A gas used to pressurize the mold cavity to control the expansion of the foamed melt.
Dynamically applies varying pressures
(Claim 1, Claim 17, Claim 20)
“For instance, using this GCP process a pressurized mold cavity may be injected with an SCF, which alone and together may function to counteract the expansion of the gas within the melt. Particularly, as the counter pressure is released, the gas bubbles that would conventionally breakthrough the surface are trapped inside, creating a smooth skin. This gas counter pressure process prevents the gas bubbles from contacting and breaking through the surface of the foaming material as the foamed part is formed.”The control unit of the molding apparatus is configured to change the pressure of the counterpressure gas within the mold cavity during the foaming process.
Single-phase solution
(Claim 1, Claim 17, Claim 20)
“The creation of the single-phase solution, in which the SCF is fully dissolved and uniformly dispersed in the molten polymer, takes place inside the injection barrel under carefully controlled process conditions: the SCF must be accurately mass flow metered into the polymer for a fixed amount of time. And during that dosing period, the right conditions of temperature, pressure and shear must be established within the barrel. Back-pressure, screw-speed and barrel-temperature control, as well as gas counter pressure and SCF delivery system all play a role in establishing the process conditions that create the single-phase solution.”A mixture of molten polymer and supercritical fluid, where the supercritical fluid is fully dissolved and uniformly dispersed within the molten polymer.
Supercritical fluid
(Claim 1, Claim 17, Claim 20)
“Specifically, a supercritical fluid is a substance (liquid or gas) that is in a state above its critical temperature (Tc) and critical pressure (Pc). At this critical point gases and liquids coexist, and a supercritical fluid shows unique properties that are different from those of either liquids or gases, e.g., under standard conditions. It is advantageous to use inert supercritical fluid, such as nitrogen, CO2, He, Ne, Ar, Xe, and other such inert gasses, such as in a supercritical fluid state, which gasses that may be employed in accordance with the methods disclosed herein as a blowing agent in the foaming process.”A substance (liquid or gas) that is in a state above its critical temperature and critical pressure, used as a foaming agent.
Thermoplastic masterbatch
(Claim 1, Claim 17, Claim 20)
“Blends of two or more thermoplastic polymers provide a combination of properties and price not found in a single polymer. There are a number of ways to blend polymers together successfully. One method may use twin-screw extrusion to melt two or more polymer resins together and to then extrude the molten polymer resin blend into a strand that is cooled and fed into a pelletizer for producing an array of pelletized pieces called a masterbatch.”A blend of one or more recyclable thermoplastic polymers, possibly with fillers and additives, prepared for foaming.

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US12194704

O2 PARTNERS LLC
Application Number
US18366177
Filing Date
Aug 7, 2023
Status
Granted
Expiry Date
May 21, 2039
External Links
Slate, USPTO, Google Patents