Colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing same

Patent No. US7241500 (titled "Colored roofing granules with increased solar heat reflectance, solar heat-reflective shingles, and process for producing same") on Oct 6, 2003. The application was issued on Jul 10, 2007.

What is this patent about?

’500 is related to the field of asphalt roofing shingles and the protective granules used to coat them. Specifically, it addresses the thermal challenges of dark-colored roofs, which typically absorb significant solar heat in the near-infrared spectrum. This absorption leads to elevated surface temperatures, increased cooling costs for buildings, and the contribution to urban heat-island effects. The invention seeks to provide roofing granules that maintain aesthetically pleasing, deep-tone colors while achieving high solar reflectance.

The underlying idea behind ’500 is the strategic decoupling of visible color from infrared absorption through specialized multi-layer coatings and advanced pigments. Rather than relying on traditional metal oxides that absorb heat, the invention utilizes infrared-reflective functional pigments—such as light-interference platelets or mirrorized silica—that reflect heat even when they appear dark to the eye. By layering these pigments over a highly reflective white base coat or incorporating them into a transparent outer shell, the granules can mimic the appearance of conventional shingles while rejecting a much higher percentage of solar radiation.

The claims of ’500 focus on several structural configurations for roofing granules that utilize a binder and at least one infrared-reflective component. These include granules where a single coating contains a colored, infrared-reflective pigment, as well as multi-layer systems where an inner coating provides a reflective white foundation (using titanium dioxide or zinc oxide) and an outer coating provides the visible color. The claims also encompass designs where a color-providing inner layer is shielded by an infrared-reflective functional pigment in the outer layer, specifically targeting shingles with low lightness values but high solar reflectance.

In practice, the invention works by applying these specialized coating compositions to mineral particles ranging from #8 to #70 mesh size. The binders can be inorganic silicates cured at high temperatures or organic polymers that allow for lower-temperature processing and improved moisture resistance. By using light-interference platelet pigments based on mica or alumina, the granules achieve a pearlescent effect that effectively scatters near-infrared light. This allows for the production of shingles with a lightness value (L*) of less than 60—appearing as deep browns, reds, or grays—that still exceed a solar reflectance threshold of 25%.

This approach differs from prior solutions that relied on simple metal oxide coatings or aluminum flakes, which often struggled to balance aesthetic variety with thermal performance. Traditional dark shingles typically reflect only 5-15% of solar heat; however, the multi-layer architecture described here allows the granule to reflect heat that has already penetrated the outer color layer by bouncing it off the white internal primer. This dual-action mechanism significantly reduces the thermal stress on the underlying asphalt substrate, extending the service life of the roofing material while maintaining the deep-tone colors preferred in residential architecture.

How does this patent fit in bigger picture?

Technical Landscape

In the early 2000s when ’500 was filed, the production of colored roofing materials was typically implemented using mineral granules coated with metal-oxide pigments and alkaline silicate binders. At a time when systems commonly relied on standard pigment formulations to achieve specific aesthetic color profiles, the thermal performance of dark-colored shingles was limited by the high solar absorption of these conventional materials, particularly in the near-infrared spectrum. Engineering constraints of the era made it non-trivial to achieve high solar reflectance in deep-tone or dark roofing products, as the pigments required for these colors naturally absorbed significant thermal energy, leading to elevated roof temperatures and increased cooling loads.

Prosecution Position

The disclosed invention achieves a technical advancement in solar-reflective building materials through an architectural shift in granule coating design. By integrating infrared-reflective functional pigments—such as light-interference platelet pigments, mirrorized silica, or solid-solution iron oxides—into a multi-layered coating structure, the invention enables high solar heat reflectance even in dark-colored shingles. The structural solution involves a dual-layer approach where a highly reflective white base coating is paired with a color-providing top coating, or alternatively, a color coating is paired with a transparent, infrared-reflective outer layer. This configuration overcomes the constraint of thermal absorption in dark pigments, achieving a solar reflectance of at least 20 percent while maintaining deep-tone aesthetics and color stability.

Claims

The patent contains a total of 33 claims, with claims 1, 6, 8, 13, 17, 23, 28, 32, and 33 serving as the independent claims. These independent claims focus on colored infrared-reflective roofing granules featuring specific mesh sizes and multi-layered coatings, bituminous roofing products incorporating these granules, a mineral-surfaced asphalt shingle defined by specific solar reflectance and lightness values, and a process for manufacturing these roofing materials. The dependent claims serve to further define the invention by specifying particular pigment types, such as titanium dioxide or light-interference platelets, and establishing narrow performance thresholds for infrared reflectance and color values.

Key Claim Terms New

Definitions of key terms used in the patent claims.

Term (Source)Support for SpecificationInterpretation
Colored, infrared-reflective pigment
(Claim 1, Claim 6, Claim 17, Claim 33)
Specifically, colored, infrared-reflective pigments, such as those comprising a solid solution including iron oxide, can be employed. The colored, infrared-reflective pigment can also comprise a near infrared-reflecting composite pigment composed of a near-infrared non-absorbing colorant of a chromatic or black color and a white pigment coated with the near infrared-absorbing colorant.A pigment that provides both a specific visual color (L* < 85) and high reflectance in the near-infrared range (700 nm-2500 nm) of the solar spectrum.
Granule coloring pigment
(Claim 8, Claim 13, Claim 23, Claim 28)
As used in the present specification and claims, 'granule coloring pigment' denotes a conventional metal oxide-type pigment employed to color roofing granules. These can be conventional granule coloring pigments based on metal oxides, or colored infrared-reflective pigments.A conventional metal oxide-type pigment used to provide aesthetic color to roofing granules, distinct from specialized infrared-reflective pigments.
Infrared-reflective functional pigment
(Claim 13, Claim 28)
Infrared-reflective functional pigments include light-interference platelet pigments including titanium dioxide, light-interference platelet pigments based on metal oxide coated-substrate, mirrorized silica pigments based upon metal-doped silica, and alumina. These 'pearlescent' pigments based on metal oxide-coated substrates allow additional solar reflection to achieve both colors and increased solar heat reflection.A specialized pigment that enhances solar heat reflectance through physical structures or material properties, specifically selected from light-interference platelets, mirrorized silica, or alumina.
Light-interference platelet pigments
(Claim 13, Claim 28)
Light-interference platelet pigments based on metal oxide coated-substrates are preferably selected from those pigments constructed from partially opaque substrates, such as mica, alumina, or silica, and metal-oxide coatings having light-interference properties.Pigments constructed from partially opaque substrates with metal-oxide coatings that utilize light interference to provide color and infrared reflectance.
Reflective white pigment
(Claim 6, Claim 8, Claim 23)
The reflective white pigment is preferably selected from the group comprising titanium dioxide, zinc oxide and zinc sulfide. The inner coating is used to reflect most solar radiation that has penetrated the color coating in order to improve the overall solar heat reflectance.A pigment used in a base coating layer to reflect solar radiation that penetrates the outer color layer, typically having a solar heat reflectance of at least 60 percent.

Litigation Cases New

US Latest litigation cases involving this patent.

Case NumberFiling DateTitle
3:25-cv-00699Mar 24, 2025Certainteed Llc V. Gaf Materials Llc

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US7241500

Application Number
US10679898A
Filing Date
Oct 6, 2003
Publication Date
Jul 10, 2007
External Links
Slate, USPTO , Google Patents