Method for fabricating semiconductor device

Patent No. US7365000 (titled "Method for fabricating semiconductor device") on Jun 28, 2004. The application was issued on Apr 29, 2008.

What is this patent about?

’000 is related to the field of semiconductor fabrication, specifically the creation of self-aligned contacts in high-density integrated circuits. As device dimensions shrink below 80nm, the aspect ratio between conductive structures like gate electrodes increases, making it difficult for traditional insulation materials to fill narrow gaps without leaving voids or suffering damage during subsequent wet cleaning steps.

The underlying idea behind ’000 is a hybrid insulation strategy that leverages the specific strengths of two different flowable materials to eliminate structural defects. By using a spin-on-glass (SOG) layer specifically for the narrow bottom gaps and an advanced planarization layer (APL) for the upper bulk insulation, the process avoids the micro-voids typical of APL in tight spaces while ensuring the SOG is thin enough to be fully densified during curing.

The claims of ’000 focus on a multi-stage fabrication sequence that includes forming conductive structures, depositing and curing a spin-on-glass layer, and then overlaying an advanced-planarization-layer to complete the composite insulation stack. The method specifically requires a wet cleaning step using a hydrofluoric acid (HF) or buffered oxide etchant (BOE) solution for a duration of 10 to 200 seconds to prepare the resulting contact holes.

In practice, the SOG layer is deposited with a controlled thickness that ensures the subsequent thermal curing process can penetrate and densify the material all the way to the bottom of the trench. This densification is critical because it provides the chemical resistance necessary to withstand the wet cleaning agents that would otherwise cause lateral erosion or 'pitting' in under-cured dielectric material.

This approach differentiates itself from prior methods by preventing the micro-voids that often form when APL is forced into high-aspect-ratio trenches, which can lead to electrical shorts or 'punches' during etching. By restricting the SOG to a thickness that allows for a complete cure, the invention provides a robust, planarized insulation stack that maintains structural integrity and precise contact dimensions even after aggressive chemical cleaning.

How does this patent fit in bigger picture?

Technical Landscape

In the early 2000s when ’000 was filed, semiconductor fabrication was transitioning toward sub-100nm design rules at a time when inter-layer dielectric gap-filling was typically implemented using high-temperature thermal flow processes like Borophosphosilicate Glass (BPSG). When systems commonly relied on these thermal processes, the resulting lateral diffusion of dopants often compromised the integrity of increasingly dense conductive patterns. As aspect ratios for gate electrodes increased, hardware constraints made achieving a void-free, chemically stable insulation layer non-trivial, forcing a shift toward flowable dielectrics such as Spin-on-Glass (SOG) or Advanced Planarization Layers (APL). However, these materials frequently exhibited non-uniform density or micro-voids, making them susceptible to structural failure or excessive erosion during subsequent wet cleaning and etching stages.

Prosecution Position

The disclosed invention represents a technical advancement through a hybrid architectural approach to inter-layer insulation that overcomes the density gradients inherent in single-layer dielectric applications. By integrating a cured SOG layer with a secondary APL layer prior to the self-aligned contact (SAC) etching process, the solution achieves a composite dielectric stack that maintains high gap-fill capability while mitigating the structural weaknesses of the individual materials. This specific integration enables the formation of high-aspect-ratio contact holes without the typical risks of inter-layer damage or 'punches' caused by micro-voids. The technical effect is a more robust insulation profile that withstands aggressive wet cleaning processes, ensuring reliable electrical isolation in ultra-fine pitch semiconductor devices.

Claims

The patent contains a total of 13 claims, with claim 1 serving as the sole independent claim. This independent claim focuses on a method for fabricating a semiconductor device that involves forming an insulation layer from a combination of spin-on-glass and advanced-planarization layers, followed by a specific contact hole cleaning process using a heavy water and fluorine oxide solution for a defined duration. The dependent claims serve to further specify the manufacturing parameters, such as the chemical composition of the source gases, the temperature and atmospheric conditions for curing, the specific materials used for conductive structures and etch stops, and the particular techniques employed for plug formation and self-aligned etching.

Key Claim Terms New

Definitions of key terms used in the patent claims.

Term (Source)Support for SpecificationInterpretation
Advanced-planarization-layer
(Claim 1)
Examples of the flowable insulation layer are an advanced planarization layer (APL) and a spin on glass (SOD) layer. The invention provides a method capable of overcoming defects caused by an improper contact opening in a certain region and a plurality of punches taken place by micro voids of an APL layer.A flowable insulation layer (APL) deposited on top of a spin-on-glass layer to form a composite insulation structure, used to mitigate defects such as micro voids or density variations.
Cleaning the contact holes
(Claim 1)
The present invention relates to a method for fabricating a semiconductor device capable of preventing an inter-layer insulation layer from being damaged during a wet cleaning process due to a difference in density created by reliance on a thickness of a SOG layer subjected to a curing process. A bottom part of the SOG layer is not sufficiently densified, thereby being susceptible to a wet cleaning process performed after a contact formation process.A wet cleaning process performed after contact hole formation using a specific concentration of HF or BOE for a duration of 10 to 200 seconds to prepare the contact area.
Curing
(Claim 1)
However, it is essential to densify the SOG layer through a curing process at a temperature ranging from 600° C. to 700° C. A bottom part of the SOG layer is not sufficiently densified, thereby being susceptible to a wet cleaning process performed after a contact formation process.A thermal process performed at specific temperatures to densify a flowable insulation layer, such as SOG, to improve its resistance to subsequent wet cleaning processes.
Selectively etching
(Claim 1)
A self-aligned contact (SAC) etching process is required to form such a LPC. The SAC etching process is a method of forming a contact by carrying out an etching process to a bottom semiconductor structure having a specific etch selectivity ratio. Generally, the SAC etching process uses materials e.g., nitride and oxide having a different etch selectivity ratio.A self-aligned contact (SAC) etching process that removes specific portions of the insulation layers (APL and SOG) based on etch selectivity ratios to expose the substrate.
Spin-on-glass layer
(Claim 1)
Examples of the flowable insulation layer are an advanced planarization layer (APL) and a spin on glass (SOD) layer, which is also called a spin on dielectric (SOD) layer. For the SOG layer, it has a good gap fill property. However, it is essential to densify the SOG layer through a curing process at a temperature ranging from 600° C. to 700° C.A flowable insulation layer, also referred to as a spin on dielectric (SOD) layer, characterized by a high gap-fill property and requiring a curing process for densification.

Litigation Cases New

US Latest litigation cases involving this patent.

Case NumberFiling DateTitle
2:24-cv-09763Oct 14, 2024TREACE MEDICAL CONCEPTS, INC. v. STRYKER CORPORATION et al

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US7365000

Application Number
US10876783A
Filing Date
Jun 28, 2004
Publication Date
Apr 29, 2008
External Links
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