Patent No. US9789036 (titled "Peroxide gel compositions") on May 12, 2015. The application was issued on Oct 17, 2017.
’036 is related to the field of dental treatment compositions, specifically focusing on stable, high-concentration peroxide gels used for tooth whitening. Traditional thickening agents often degrade rapidly when exposed to the aggressive oxidizing power of pure hydrogen peroxide, leading to short shelf lives and reduced efficacy. Furthermore, conventional liquid or fluidic gels are difficult to manage, often leaking from delivery trays or being washed away by saliva before the treatment is complete.
The underlying idea behind ’036 is the utilization of poly(2-ethyl-2-oxazoline) as a specialized thickening agent that remains stable even in high-concentration peroxide environments. Unlike standard polymers that break down into watery consistencies, this specific polymer allows for hydrogen peroxide concentrations of 30% or higher while maintaining a six-month shelf life at room temperature. The invention transforms this mixture into a gelatinous, visco-elastic state that behaves like a flexible solid, resisting flow and dilution until it is intentionally activated by the user.
The claims of ’036 focus on a dental whitening composition comprising a thickening agent consisting of poly(2-ethyl-2-oxazoline), a peroxide active, and a solvent. The independent claims specifically define the physical state of the composition as a gelatinous compound with unique deformation properties: it is flexible enough to bend and conform to a container's shape, yet sufficiently cohesive that discrete pieces of the material will not merge or coalesce into a single body when placed together under standard temperature and pressure.
In practice, the composition is applied to a flexible backing and dried to reach its characteristic gummi-like consistency. This dry-to-the-touch state makes the product easy to handle and package without the mess associated with fluidic gels. When a user is ready for treatment, they simply hydrate the surface with water to restore its adhesiveness, allowing the tray to be pressed and molded directly against the dental arch. This creates a custom-fitted barrier that holds the high-potency peroxide against the teeth while shielding it from saliva.
This approach differentiates itself from the prior art by eliminating the need for complex two-part mixing systems or uncomfortable, rigid pre-formed trays. By achieving a stable high-concentration peroxide gel that does not decompose, the invention allows for significantly shorter treatment times—often just three days compared to a week or more for lower-concentration products. The resulting device functions as a truly customizable, formable tray that provides the potency of a professional clinical treatment in a convenient, shelf-stable home format.
In the mid-2000s when ’036 was filed, dental whitening systems were typically implemented using fluidic gels or liquids that relied on carbamide peroxide or other stabilized adducts to maintain shelf life. At a time when standard thickening agents like carbomer polymers were the industry norm, system architectures were limited by the fact that these thickeners would rapidly degrade and lose viscosity when exposed to high concentrations of pure hydrogen peroxide. Furthermore, delivery systems commonly relied on rigid custom-molded trays or thin plastic strips, where the fluidic nature of the treatment gel made application non-trivial due to material run-off, saliva dilution, and mechanical displacement during use.
The disclosed invention represents a meaningful technical advancement through the integration of Poly(2-ethyl-2-oxazoline) as a specialized thickening agent that is chemically compatible with high-concentration hydrogen peroxide. This architectural shift from unstable carbomer-based gels to a Poly(2-ethyl-2-oxazoline) matrix enables the creation of a pre-mixed, shelf-stable, visco-elastic composition that maintains its structural integrity without the rapid oxidative degradation seen in the prior art. The technical effect achieved is a hygroscopic, gelatinous treatment material that can be conjoined to a flexible backing to form a conformable dental tray. This solution overcomes the technical constraints of fluidic delivery by providing a material that is sufficiently rigid to resist pumping and displacement, yet becomes adhesive upon wetting to conform to irregular dental surfaces.
This patent contains a total of 20 claims, with claims 1, 9, and 15 serving as the independent claims. These independent claims focus on a dental whitening and bleaching composition featuring a specific thickening agent, a peroxide active, and a solvent, characterized by a gelatinous physical state that conforms to containers while resisting merging between separate pieces. The dependent claims serve to further define the chemical components, specifying particular peroxide types, solvent varieties, molecular weight ranges for the thickening agent, viscosity levels, and precise concentration percentages for the hydrogen peroxide.
Definitions of key terms used in the patent claims.
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